Process for producing menthone

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260586C, 568829, 568875, C07C 4500, C07C 4516

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active

041349199

ABSTRACT:
A process for producing menthone comprising dehydrogenating citronellol in the presence of a dehydrogenation catalyst at about 150 to about 260.degree. C in an atmosphere of hydrogen under a pressure of 0 to about 5 kg/cm.sup.2. G and a process for producing menthol. Since the dehydrogenation catalyst has a hydrogenating ability, an embodiment additionally includes the ability to ultimately produce menthol in the same reactor without separating the catalyst or adding additional or another catalyst to the system by simply changing the temperature and the hydrogen pressure. Embodiments also include producing menthone and also ultimately menthol utilizing geraniol or a mixture of geraniol and citronellol as a starting material again without catalyst separation or use of additional or another catalyst.

REFERENCES:
patent: 1811711 (1931-06-01), Blagdin
patent: 3405185 (1968-10-01), Houlihan et al.
patent: 3870761 (1975-03-01), Pasedach et al.
patent: 4058571 (1977-11-01), Budermann
Kogami et al., "Bull. Chem. Soc. Japan", 41, 2508-2514 (1968).
Treibs et al., "Ber", 60, 2335-2341, (1927).

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