Monomer and polymer for photoresist, and photoresist using the s

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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4302701, 526318, 526319, G03F 7028

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active

061329363

ABSTRACT:
The present invention relates to a new monomer of a lithocholylacrylate type, a new photoresist copolymer prepared from the new monomer, a new photoresist composition and processes for preparing same. The photoresist of the present invention may be used in lithography processes using KrF(248 nm) or ArF(193 nm) light sources which are typically used in the manufacture of 1G or 4G DRAM semi-conductor integrated circuits. The new monomer of the present invention is represented by following Formula II: ##STR1## wherein, R.sub.1 represents hydrogen, a substituted or non-substituted C.sub.1 -C.sub.10 straight or branched chain alkyl group, a cycloalkyl group, an alkoxyalkyl group, or a cycloalkoxyalkyl group; and R.sub.2 represents hydrogen or a methyl group. A representative new photoresist copolymer of the present invention is represented by the following Formula VII: ##STR2## wherein, R.sub.1 and R.sub.2 independently represent hydrogen or a methyl group, and x and y independently represent a mole fraction between 0.05 and 0.9.

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