Removal of sulfur-containing impurities from volatile metal...

Specialized metallurgical processes – compositions for use therei – Processes – Free metal or alloy reductant contains magnesium

Reexamination Certificate

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C423S244010

Reexamination Certificate

active

10717050

ABSTRACT:
Method for the purification of a volatile metal hydride comprising obtaining a volatile metal hydride feed containing one or more acidic impurities, one of which is a sulfur-containing impurity; contacting the feed with an alkaline material and reacting at least a portion of the sulfur-containing impurity with the alkaline material to remove a portion of the sulfur-containing impurity from the feed and provide an intermediate purified material, wherein the contacting of the feed with an alkaline material is effected at a sub-ambient temperature; and contacting the intermediate purified product with an adsorbent material to remove at least a portion of the sulfur-containing impurity from the intermediate purified material and provide a purified volatile metal hydride product.

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A.A. Efremov, et al, Absorption-Adsorption Process for Purification of Volatile Inorganic Hydrides, Amer. Chem. Soc., 6001 Chem. Abstracts, 114, Apr. 1991, 22, No. 16.
Tolmachev, A.M., et al., “Deep Purification of Hydrides by the Adsorption Method. I. Selectivity of Zeolites for Various Hydrides”, Vysokochistye veshchestva 1988, No. 2, pp. 65-70, Dec. 1988.

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