Method of forming a tantalum-containing gate electrode...

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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C438S683000, C438S685000, C257SE21170

Reexamination Certificate

active

07067422

ABSTRACT:
A method for forming a tantalum-containing gate electrode structure by providing a substrate having a high-k dielectric layer thereon in a process chamber and forming a tantalum-containing layer on the high-k dielectric layer in a thermal chemical vapor deposition process by exposing the substrate to a process gas containing TAIMATA (Ta(N(CH3)2)3(NC(C2H5)(CH3)2)) precursor gas. In one embodiment of the invention, the tantalum-containing layer can include a TaSiN layer formed from a process gas containing TAIMATA precursor gas, a silicon containing gas, and optionally a nitrogen-containing gas. In another embodiment of the invention, a TaN layer is formed on the TaSiN layer. The TaN layer can be formed from a process gas containing TAIMATA precursor gas and optionally a nitrogen-containing gas. A computer readable medium executable by a processor to cause a processing system to perform the method and a processing system for forming a tantalum-containing gate electrode structure are also provided.

REFERENCES:
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patent: 2002/0115886 (2002-08-01), Yasuhara et al.
patent: 2002/0192952 (2002-12-01), Itoh et al.
patent: 2003/0008501 (2003-01-01), Bakli et al.
patent: 2003/0017697 (2003-01-01), Choi et al.
patent: 2005/0082625 (2005-04-01), Kim et al.
patent: 2005/0104142 (2005-05-01), Narayanan et al.
Seong Geon Park et al.,Performance Improvement of MOSFET with HfO2-Al2O3Laminate Gate Dielectric and CVD-TaN Metal Gate Deposited by TAIMATA,IEDM Technical Digest, Washington, D.C., Dec. 8, 2003, pp. 327-330.
V. Narayanan et al.,Dual Work Function Metal Gate CMOS Using CVD Metal Electrodes,VLSI Technology, Digest of Technical Papers, Symposium, Honolulu, HI, Jun. 15, 2004, pp. 192-193.

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