Substituted barium titanate and barium strontium titanate...

Compositions: ceramic – Ceramic compositions – Titanate – zirconate – stannate – niobate – or tantalate or...

Reexamination Certificate

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C501S139000, C333S161000, C250S250000

Reexamination Certificate

active

07094721

ABSTRACT:
This invention provides the three novel La,Fe, La,Cr and Sm,Fe substituted barium titanate solid solution ferroelectric compositions with the formula Ba1−xLnxTi1−xMxO3wherein when Ln is La, M is Fe or Cr, when Ln is Sm, M is Fe and x is from about 0.02 to about 0.06 and mixtures thereof, the novel La,Fe substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1−ySry)1−xLaxTi1−xFexO3wherein y is greater than zero and less than about 0.6 and x is from about 0.01 to about 0.06 and the novel La,Al substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1−ySry)1−xLaxTi1−x/4−3a/4Ala}(x−a)/4O3wherein } denotes a vacancy, y is greater than zero and less than about 0.6, a is from about 0.01 to about 0.06 and x is from 0.02 to about 0.10 with the proviso that x is greater than or equal to a.These low loss tunable ferroelectric compositions are especially useful in tunable microwave thin film devices which fall into three types: interdigital and trilayer capacitors, coplanar waveguides and microstrips.

REFERENCES:
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patent: 5472935 (1995-12-01), Yandrofski et al.
patent: 63 301 409 (1988-12-01), None
S. Skapin et. al., Chemical Reactions and Dielectric Properties of the BATIO3-LALAO3-LATI3/4O3 Systems, Journal of Solid State Chemistry, 1997, pp. 223-230, vol. 129, Ljubljana Slovenia.
A. Inoueet. Al., Effect of Iron-Group-Ion Doping on the Properties of BATIO3 Ceramics, Institute of Applied Physics, 1991, pp. 2388-2390, vol. 30, No. 9A, Sakura, Ibaraki.
Hagemann, H.J. et. al., Reversible Weight Change of Acceptor-Doped BATIO3, Journal of The American Ceramic Society, 1981, pp. 590-594, Federal Republic of Germany.
Sengupta et. al., Breakthrough Advances in Low Loss, Tunable Dielectric Materials, Mat. Res. Innovat., 1999, pp. 278-282.
I.H. Ismailzade et. al., The Magnetoelectric (ME) H Effect at the Ferroelectric and Antiferroelectric Phase Transitions, Department of Radiation Investigations, Academy of Sciences of the Azerbaidzhan SSR, USSR.
Dong Li et. al., Novel Tunable Ferroelectric Compositions: BA1 LN TI MO (LN = LA. SM. GD, DY.M = AL. FE CR); Solid State Sciences 2, 2000, pp. 507-512, Elsevier.
S. Skapin et. al., Chemical Reactions and Dielectric Properites of the BATIO-3-LAIO3 and BATIO3—LAAIO3—LAR13/4O3 Systems; Journal of Solid State Chemistry, 129, pp. 223-230, 1997, Academic Press.
J. Schwarzbach; Semiconducting Ceramic Barium Lanthanum Titanate Doped with Iron; Czech. J. Phys.B 18, 1988, pp. 1322-1334.

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