Multi-layered barrier metal thin films for Cu interconnect...

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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C438S627000, C438S643000, C438S648000, C438S656000, C438S687000

Reexamination Certificate

active

07015138

ABSTRACT:
A multi-layered barrier metal thin film is deposited on a substrate by atomic layer chemical vapor deposition (ALCVD). The multi-layer film may comprise several different layers of a single chemical species, or several layers each of distinct or alternating chemical species. In a preferred embodiment, the multi-layer barrier thin film comprises a Tantalum Nitride layer on a substrate, with a Titanium Nitride layer deposited thereon. The thickness of the entire multi-layer film may be approximately fifty Angstroms. The film has superior film characteristics, such as anti-diffusion capability, low resistivity, high density, and step coverage, when compared to films deposited by conventional chemical vapor deposition (CVD). The multi-layered barrier metal thin film of the present invention has improved adhesion characteristics and is particularly suited for metallization of a Copper film thereon.

REFERENCES:
patent: 6284646 (2001-09-01), Leem
patent: 6368954 (2002-04-01), Lopatin et al.
patent: 6391785 (2002-05-01), Satta et al.
patent: 6703708 (2004-03-01), Werkhoven et al.

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