In-situ monitoring and control of germanium profile in...

Single-crystal – oriented-crystal – and epitaxy growth processes; – Forming from vapor or gaseous state – With a step of measuring – testing – or sensing

Reexamination Certificate

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C117S086000, C117S939000, C117S935000, C118S715000

Reexamination Certificate

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06881259

ABSTRACT:
Analysis of residual gases from a process for depositing a film containing silicon on a crystalline silicon surface to determine partial pressure of hydrogen evolved during deposition develops a signature which indicates temperature and/or concentration of germanium at the deposition surface. Calibration and collection of hydrogen partial pressure data at a rate which is high relative to film deposition rate allows real-time, in-situ, non-destructive determination of material concentration profile over the thickness of the film and/or monitoring the temperature of a silicon film deposition process with increased accuracy and resolution to provide films of a desired thickness with high accuracy.

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patent: 6015478 (2000-01-01), Satoh
Maley et al., “Infrared reflectance spectroscopy of very thin films of hydrogenated amorphous silicon”, J. Non-crystalline Solids., vol. 114 (1) 1989 pp. 163-165 abstract only.*
Abelson et al., “Surface hydrogen release during the growth of a-Si:H by reactive magnetron sputtering”, Journal of Vacuum Science and Technology A vol. 8, No. 3 pt. 1 pp. 1364-1368 May-Jun. 1990 abstract only.*
Pejnefors et al.' “Chemical vapor deposition of undoped and in-situ boron and arsenic doped epitaxial and polycrstalline silicon films grown using silane at reduced pressure”, Journal of Applied Physics vol. 88 No. 3 pp. 1655-1663 Aug. 2000.*
L.L. Tedder et al.; “Real-Time Process and Product Diagnostics in Rapid Thermal Chemical Vapor Deposition Using In Situ Mass Spectrometric Sampling”; J. Vac. Sci. Technol. Jul./Aug. 1995; pp. 1924-1927.

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