Semiconductor device and manufacturing method thereof

Active solid-state devices (e.g. – transistors – solid-state diode – Field effect device – Having insulated electrode

Reexamination Certificate

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C257S506000, C257S632000, C257S640000, C257S649000, C257S324000

Reexamination Certificate

active

06707099

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor device having element isolation regions and to a manufacturing method thereof.
2. Description of the Background Art
FIGS. 67
to
76
are diagrams that show the process steps of a conventional semiconductor device manufacturing method. Such a manufacturing method is described in, for example, “IEEE Transaction on Electron Devices,” Vol. ED-33, No. 11 November 1986, PP. 1659-1666.
FIGS. 67
to
76
are all cross-sectional views that show an MOS (Metal Oxide Semiconductor) transistor in the gate width direction.
First, thermal oxidation is applied to the surface of a semiconductor substrate
1
, a silicon substrate, to form a silicon oxide film
2
(FIG.
67
). Next, photoresist
3
is applied on the silicon oxide film
2
. Then, in order to form the active region of the MOS transistor, an opening
3
a
is formed in the photoresist
3
by using photolithography technique (FIG.
68
).
Subsequently, dry etching is selectively applied in the opening
3
a
by using the photoresist
3
as a mask, so as to remove the part of the silicon oxide film
2
right under the opening
3
a
. An opening
4
for the formation of the active region is thus formed in the silicon oxide film
2
(FIG.
69
). This process step also forms the silicon oxide film
2
as element isolation regions.
Next, an epitaxial silicon layer
5
is formed in the active region formation opening
4
by selective epitaxial growth (FIG.
70
). In this process step, the epitaxial silicon layer
5
is formed to a sufficient height (to a level higher than the surface level of the silicon oxide film
2
) in the active region formation opening
4
. Accordingly the epitaxial silicon layer
5
is somewhat formed also on the silicon oxide film
2
.
After that, the surface is etched back or chemical-mechanical-polished (CMP) for planarization of the surface of the epitaxial silicon layer
5
(FIG.
71
). A silicon layer
6
for the active region formation is thus formed in the active region formation opening
4
. During this planarization process, the silicon oxide film
2
can be used as an etching stopper or a polishing stopper by taking advantage of the etch selectivity or polish selectivity between the epitaxial silicon layer
5
and the silicon oxide film
2
.
Next, thermal oxidation is applied to the surface of the active region formation silicon layer
6
to form a sacrificial silicon oxide film
7
(FIG.
72
). Then ion implantation
8
for well and channel formation is applied through the sacrificial silicon oxide film
7
(FIG.
73
). The sacrificial silicon oxide film
7
is a sacrificed layer which sacrificially undergoes damage during the ion implantation
8
, for the active region formation silicon layer
6
and the semiconductor substrate
1
.
Then the sacrificial silicon oxide film
7
is removed by wet etching using HF (FIG.
74
). Subsequently a silicon oxide film and a polycrystalline silicon film are formed on the surface of the semiconductor substrate
1
, which are then patterned to form a gate oxide film
10
and a gate electrode
12
of the MOS transistor (FIG.
75
).
According to this conventional semiconductor device manufacturing method, the silicon oxide film
2
is formed into the element isolation regions in the steps of
FIGS. 68 and 69
through photolithography and etching techniques. Hence the element isolation regions are free from bird's beaks, as would be caused by LOCOS (Local Oxidation of Silicon), and also free from seams and voids, as would be caused by the trench isolation. The element isolation regions therefore provide good insulation.
In the conventional semiconductor device manufacturing method shown above, however, as shown in
FIG. 74
, recesses
9
are likely to form in the silicon oxide film
2
during the removal of the sacrificial silicon oxide film
7
. The removal of the sacrificial silicon oxide film
7
uses not dry etching but wet etching, so as to prevent further damage. Since the wet etching is isotropic, it is likely to remove the parts of the silicon oxide film
2
which are located at the edges of the sacrificial silicon oxide film
7
, thus forming the recesses
9
.
FIG. 76
is a diagram that shows the region
11
in
FIG. 75
in an enlarged manner.
Now, in MOS transistors, it is desired that the channel width W and the threshold voltage Vth be in a relation as shown by the graph GR
1
in FIG.
77
. That is to say, it is desired that the threshold voltage Vth keep a constant value irrespective of the channel width W.
However, in reality, as shown by the graph GR
2
in
FIG. 77
, the threshold voltage Vth decreases as the channel width W diminishes: this is a so-called inverse narrow channel effect. When the inverse narrow channel effect is noticeable, it reduces the design margin of the MOS transistor. Especially, in devices with reduced dimensions, the threshold Vth greatly varies with dimensional variations, leading to unstable operations of the MOS transistors.
It is thought that the inverse narrow channel effect is caused by influence of the electric fields at the gate edges in the gate-width direction. That is to say, it is supposed that the inverse narrow channel effect becomes more noticeable as the electric fields
11
a
and
11
b
at the gate edge in
FIG. 76
become stronger.
The recess
9
in the silicon oxide film
2
causes the material of the gate electrode
12
to form in an acute angle in the recess
9
, which increases the strength of the electric field
11
a
upon application of the gate voltage. Accordingly, the conventional semiconductor device manufacturing method shown above results in MOS transistors that are likely to induce the inverse narrow channel effect; the method thus involves difficulties in manufacturing MOS transistors with good characteristics.
SUMMARY OF THE INVENTION
An object of this invention is to provide a semiconductor device which is less likely to induce the inverse narrow channel effect and a manufacturing method thereof.
According to a first aspect of the invention, a semiconductor device includes: a semiconductor substrate; element isolation regions made of a silicon nitride film provided on the semiconductor substrate; and a semiconductor layer formed by epitaxial growth in a region interposed between the element isolation regions on the semiconductor substrate.
A semiconductor device has element isolation regions made of a silicon nitride film provided on a semiconductor substrate and a semiconductor layer formed by epitaxial growth in a region interposed between the element isolation regions on the semiconductor substrate. Accordingly, when a sacrificial layer of silicon oxide film is formed in the surface of the semiconductor layer, ion implantation is applied through the sacrificial layer, and then the sacrificial layer is removed by etching, recesses are less likely to be formed by the etching in the element isolation regions. As a result, when a gate electrode is formed on the surface of the semiconductor layer, the gate electrode is not formed in acute angles on the element isolation regions, and a semiconductor device which is less susceptible to the inverse narrow channel effect can thus be obtained.
According to a second aspect, a semiconductor device includes: a semiconductor substrate; element isolation regions made of a silicon oxynitride film provided on the semiconductor substrate; and a semiconductor layer formed by epitaxial growth in a region interposed between the element isolation regions on the semiconductor substrate.
A semiconductor device has element isolation regions made of a silicon oxynitride film provided on a semiconductor substrate and a semiconductor layer formed by epitaxial growth in a region interposed between the element isolation regions on the semiconductor substrate. Accordingly, when a sacrificial layer of silicon oxide film is formed in the surface of the semiconductor layer, ion implantation is applied through the sacrificial layer, and then the sacrificial layer is remove

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