Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making
Reexamination Certificate
1998-10-16
2003-06-03
Baxter, Janet (Department: 1752)
Radiation imagery chemistry: process, composition, or product th
Imaging affecting physical property of radiation sensitive...
Radiation sensitive composition or product or process of making
C430S281100, C430S300000, C430S320000, C430S944000, C524S167000, C524S743000, C101S463100, C101S459000
Reexamination Certificate
active
06573022
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a photosensitive image-forming material and a photosensitive composition, which can be used as an offset printing master. More particularly, the present invention relates to a positive type photosensitive image-forming material for use with an infrared laser and a positive type photosensitive composition for use with an infrared laser, which are suitable for the so-called direct plate making and which are capable of directly making a printing plate using an infrared laser based on digital signals outputted from a computer or the like.
2. Description of the Related Art
Recently, the systems of direct plate making from digital data of computers have been attracted public attention, and the various techniques have been developed. As the systems of direct plate making from digital data of computers, (1) a system using an electrophotography, (2) a system using photopolymerization wherein an Ar laser exposure and an after-heating is carried, (3) a system formed by laminating a silver salt layer on a photosensitive resin, (4) a system of a silver master type, (5) a system formed by breaking a silicone rubber layer by the discharge breakage or laser beam, and the like, have been known.
However, in a (1) system using an electrophotographic method, image forming processes such as electrification, exposure, development and the like are complicated and, therefore, apparatus becomes complicated and large. In the method (2), since a post-heating step is required and the highly sensitive printing plate is utilized, it becomes difficult to handle the plate in an illuminated room. In the systems (3) and (4), those methods have a disadvantage such as the complicated processes and a high-cost since a silver salt is used therein.
The method utilizing a system (5) is a method which have a high level of performance comparatively, but have a problem of the removal of a remaining silicone residue on the print plate.
On the other hand, a laser technology has advanced remarkably in recent years and, particularly, high output and small-sized solid-state lasers and semiconductor lasers, which have a light emission range from the near infrared region to the infrared region, are easily available, and they are very useful as light sources for an exposure when direct plate making is performed through use of digital data.
As a conventionally known positive planographic printing plate material for an infrared laser which is used for direct plate making conventionally known, an aqueous alkali solution-soluble resin having a phenolic hydroxyl group, such as a novolak resin, etc. is used. For example, Japanese Patent Application Laid-Open (JP-A) No. 7-285275 suggests image-forming materials in which a compound, which generates heat upon absorbing light to generate heat, and various onium salts and quinonediazide compounds were adding to the aqueous alkali solution-soluble resin having a phenolic hydroxyl group, such as a novolak resin, etc. These image-forming materials form an image like that the portion of a image area can't remove since the onium salt and quinonediazide compound acts as a dissolution inhibitor of the aqueous alkali solution-soluble resin, and the portion of a non-imaged area can remove since the dissolution inhibitor is decomposed by heat and it don't exert a dissolution inhibition capability.
However, there was a disadvantage such that the place for treatment is limited under a yellow lamp in such an image-forming material, because the onium salts and quinonediazide compounds have a light absorption range in the visible radiation range(350 to 500 nm). Further, the developing property in case of using a solution having low developing capability, that is, the developing property in the under conditions is insufficient, for example, a decomposition rate of the heat decomposable material become lower when exposure is performed by using low-power laser.
Furthermore, there was a problem that the onium salts and quinonediazide compounds don't have always good compatibility with the aqueous alkali solution-soluble resin and compound which generate heat upon absorbing light, therefore, it is difficult to prepare a homogeneous coating solution and to obtain a homogeneous and stable image-forming material.
Japanese Patent Application Publication (JP-B) No. 46-27919 discloses an embodiment of forming an image by using a novolak resin without using a photosensitive compound, but there were problems that the novolak resin itself has poor solvent resistance and, therefore, the plate wear resistance is lowered by use of a cleaner and printing can not be performed by using UV ink.
SUMMARY OF THE INVENTION
Accordingly, an object of the present invention is to improve the poor image-forming property of a recording layer using an aqueous alkali solution-soluble polymer compound, and to provide a positive photosensitive image-forming material for an infrared laser and a photosensitive composition for an infrared laser which are used for the so-called direct plate making which is capable of directly making a printing plate using an infrared laser based on digital signals outputted from a computer or the like. They have characteristics as follows. The positive photosensitive image-forming material and a photosensitive composition are free from the limitations of the place to be handle, and they can be used in the conventional processing devices and the conventional printing devices, and they have an excellent plate wear resistance, and they have a stable sensitivity to the concentration of a developing solution, that is a good development latitude.
The present inventors have studied intensively. As a result, they have found that it is possible to obtain a photosensitive image-forming material having an aqueous alkali-soluble polymer compound by the forming specific layer construction in which the image-forming material can be used under a white lamp, and has a remarkably improved development latitude. Thus, the photosensitive image-forming material for use with an infrared laser of the present invention has been accomplished.
Furthermore, the present inventors have intensively studied about compounds which have an interaction with an alkali-soluble polymer compound. As a result, they have found that development latitude is remarkably broaden by adding a compound of the following specific structure. Thus, the positive photosensitive composition for an infrared laser of the present invention has been accomplished.
A first object of the present invention is to provide a positive type photosensitive image-forming material for use with an infrared laser which comprise a substrate, a layer (A) and a layer (B) wherein
the layer (A) contains not less than 50% by weight of a copolymer which contains, as a copolymerization component, not less than 10% by mol of at least one of the following monomers (a-1) to (a-3):
(a-1) a monomer having in the molecule a sulfonamide group wherein at least one hydrogen atom is linked to a nitrogen atom,
(a-2) a monomer having in the molecule an active imino group represented by the following general formula (I):
(a-3) a monomer selected from acrylamide, methacrylamide, acrylate, methacrylate and hydroxystyrene, which respectively have phenolic hydroxyl group; and
the layer (B) contains not less than 50% by weight of an aqueous alkali solution-soluble resin having a phenolic hydroxyl group,
an the layer (A) and the layer (B) are laminated on said substrate in that order wherein at least said layer (B) contains at least one compound which generates heat upon absorbing light.
A second object of the present invention is to provide a positive type photosensitive composition for use with an infrared laser which comprise at least one alkali-soluble resin, a compound generating heat upon absorbing light and at least one of compound (I) and compound (II) represented by the following formula:
R
1
—SO
2
—SO
2
—R
2
(II)
R
1
—SO
2
—R
2
(III)
wherein R
1
and R
2
may be the same
Kawauchi Ikuo
Miyake Hideo
Baxter Janet
Burns Doane , Swecker, Mathis LLP
Fuji Photo Film Co. , Ltd.
Thornton Yvette C.
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