Semiconductor memory device and manufacturing method thereof

Active solid-state devices (e.g. – transistors – solid-state diode – Field effect device – Having insulated electrode

Reexamination Certificate

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C257S307000

Reexamination Certificate

active

06483141

ABSTRACT:

FIELD OF THE INVENTION
This invention pertains to a semiconductor memory device, e.g., a DRAM (dynamic random access memory) and to a manufacturing method therefor.
BACKGROUND OF THE INVENTION
For example, with recent DRAMs, various memory capacitor structures have been proposed to maintain the required cell capacitor capacity while reducing the base area of the memory cell capacitor.
Referring to
FIGS. 10-14
, cross sections of a conventional memory cell transistor section and drain diffusion section are shown, and the manufacturing method therefor will be explained.
First, as shown in
FIG. 10
a,
for example, elements are separated by field oxide film
102
, silicon oxide (SiO
2
) film
104
is formed, as an inter-layer insulating film, over the entire surface of silicon semiconductor substrate
101
, on which is formed an access transistor structure, which includes impurity diffusion layer
103
, and others, and silicon nitride (Si
3
N
4
) film
105
is further formed on that.
Next, as shown in
FIG. 10
b,
contact hole
106
that reaches impurity diffusion layer
103
is formed in silicon nitride film
105
and silicon oxide film
104
.
Next, as shown in
FIG. 11
a,
low-resistance polysilicon film
107
is formed over the entire surface to bury contact hole
106
.
Next, as shown in
FIG. 11
b,
polysilicon film
107
is etched back, removing all of polysilicon film
107
on silicon nitride film
105
outside of contact hole
106
and leaving contact plug
107
made of this low-resistance polysilicon only in contact hole
106
. At this time, to essentially completely remove polysilicon film
107
on silicon nitride film
105
, some overetching is applied. Thus, as shown, contact plug
107
is formed slightly depressed from the top edge of contact hole
106
.
Next, as shown in
FIG. 12
a,
silicon oxide film
108
is formed over the entire surface.
Next, as shown in
FIG. 12
b,
silicon oxide film
108
is anisotropically etched to form through-hole
109
that reaches contact plug
107
.
Next, as shown in
FIG. 13
a,
low-resistance polysilicon film
110
is formed over the entire surface, including the inner surface of through-hole
109
.
Next, as shown in
FIG. 13
b,
polysilicon film
110
is etched back, essentially removing all of polysilicon film
110
on silicon oxide film
108
outside of through-hole
109
. By doing this, memory capacitor crown-type lower electrode (storage node)
110
, made of this low-resistance polysilicon, is formed in through-hole
109
.
Next, as shown in
FIG. 14
a,
silicon oxide film
108
is essentially entirely removed by wet etching using an aqueous solution of HF. At this time, silicon nitride film
105
functions as an etching stopper.
Next, as shown in
FIG. 14
b,
capacitor dielectric film
111
, composed of, for example, a stacked film of a silicon nitride film and a silicon oxide film (NO composite film), or another high dielectric material, for example, tantalum oxide (Ta
2
O
5
), barium strontium titanate (BST), lead zirconate titanate (PZT), etc., is formed to cover the surface of storage node
110
, and memory capacitor upper electrode (cell plate)
112
, made of a low-resistance polysilicon film, is further formed on that.
A crown-type memory capacitor structure is formed using the above processes.
In recent DRAMs, the length of one side of storage node
110
, laterally or longitudinally, has approached approximately the diameter of contact plug
107
, to decrease cell size smaller. For this reason, one side of through-hole
109
formed in the process in
FIG. 12
b
is approximately equal to the diameter of contact plug
107
, that is, the diameter of contact hole
106
. In addition, because of problems with bit line and storage node electric capacitance, silicon nitride film
105
cannot be thickened.
With the conventional manufacturing method discussed above, when contact plug
107
is formed with the process shown in
FIG. 11
b,
it is over-etched, so contact plug
107
is depressed approximately 100 nm from the top edge of contact hole
106
. For this reason, as shown in
FIG. 15
a,
contact plug
107
is depressed below silicon nitride film
105
, and silicon oxide film
104
is exposed at the side of contact hole
106
.
In this state, as shown in
FIG. 15
b,
if the position of through-hole
109
formed in silicon oxide film
108
is off, as shown in
FIG. 16
a,
when silicon oxide film
108
is removed by wet etching after storage node
110
is formed, as shown in
FIG. 16
b,
underlying silicon oxide film
104
is also significantly hollowed out. When upper electrode
112
intrudes into this area, it causes short-circuits and parasitic capacitance.
Because it is impossible to completely eliminate mis-positioning of through-hole
109
, when one side of storage node
110
is approximately equal to the diameter of contact plug
107
, it is extremely difficult to prevent etching of silicon oxide film
104
beneath it.
So the purpose of this invention is to provide a semiconductor memory device with a contact plug structure that prevents inadvertent etching of an underlying silicon oxide film, even when one side of the storage node is approximately equal to the diameter of the contact plug, in a DRAM such as discussed above, for example, and a manufacturing method therefor.
SUMMARY OF THE INVENTION
The semiconductor memory device of this invention, that will solve the aforementioned problems, has a semiconductor substrate provided with an impurity diffusion layer in a prescribed place in the surface region, an insulator layer provided on the aforementioned semiconductor substrate, a contact hole provided in the aforementioned insulator layer in a position on the aforementioned impurity diffusion layer, a contact plug that buries the aforementioned contact hole and that is provided projecting upward above the aforementioned insulator layer, a memory capacitor lower electrode that is provided on the aforementioned insulator layer connected to the aforementioned contact plug, a capacitor dielectric film provided on the surface of the aforementioned lower electrode, and a memory capacitor upper electrode provided on the aforementioned capacitor dielectric film.
With one embodiment of this invention, at least one side of the planar shape of the aforementioned lower electrode is approximately equal to the diameter of the aforementioned contact plug.
With one embodiment of this invention, an indented section is formed in the top surface of the aforementioned lower electrode to constitute a crown-type memory capacitor.
The semiconductor memory device manufacturing method of this invention has a process where a first insulator layer is formed over the entire surface of a semiconductor substrate where an impurity diffusion layer is formed in a prescribed place in the surface region, a process where a second insulator layer is formed over the entire surface of the aforementioned first insulator layer, a process where a third insulator layer is formed over the entire surface of the aforementioned second insulator layer, a process where a contact hole that passes through the aforementioned first through third insulator layers is formed in a position on the aforementioned impurity diffusion layer, a process where a first conductor layer is formed over the entire surface of the aforementioned third insulator layer to bury the aforementioned contact hole, a process where the aforementioned first conductor layer is etched back essentially removing all of the aforementioned first conductor layer on the aforementioned third insulator layer outside the aforementioned contact hole and at the same time leaving the aforementioned first conductor layer projecting upward at least above the aforementioned first insulator layer in the aforementioned contact hole, a process where a fourth insulator layer is formed over the entire surface, including on the aforementioned first conductor layer in the aforementioned contact hole, a process where a through-hole that reaches the aforementioned first conductor layer is formed at least in the aforemention

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