Chemical treatment for preventing copper dendrite formation and

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

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438691, 438745, 438963, H01L 2144

Patent

active

061627275

ABSTRACT:
The formation and/or growth of dendrites emanating from Cu or Cu alloy lines into a bordering open dielectric field are prevented or substantially reduced by chemically removing a portion of the surface from the dielectric field and from between the lines after CMP with a solution comprising acetic acid and ammonium fluoride. Embodiments include removing up to 60 .ANG., e.g. about 10 .ANG. to about 30 .ANG., of silicon oxide by immersing the wafer in a solution containing at least about 90 wt. % acetic acid and up to about 10 wt. % ammonium fluoride.

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patent: 5693563 (1997-12-01), Teong
patent: 5949143 (1999-09-01), Bang
patent: 6010383 (2000-01-01), Knall

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