SiCOH film preparation using precursors with built-in...

Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Insulative material deposited upon semiconductive substrate

Reexamination Certificate

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C438S789000, C438S790000, C438S781000

Reexamination Certificate

active

07915180

ABSTRACT:
A method of fabricating a dielectric material that has an ultra low dielectric constant (or ultra low k) using at least one organosilicon precursor is described. The organosilicon precursor employed in the present invention includes a molecule containing both an Si—O structure and a sacrificial organic group, as a leaving group. The use of an organosilicon precursor containing a molecular scale sacrificial leaving group enables control of the pore size at the nanometer scale, control of the compositional and structural uniformity and simplifies the manufacturing process. Moreover, fabrication of a dielectric film from a single precursor enables better control of the final porosity in the film and a narrower pore size distribution resulting in better mechanical properties at the same value of dielectric constant.

REFERENCES:
patent: 7521377 (2009-04-01), Gates et al.
patent: 2005/0230834 (2005-10-01), Schmitt et al.
Hacker, N. et al. “Properties of New Low Dielectric Constant Spin-on Silicon Oxide Based Polymers.”Mat. Res. Soc. Symp. Proc.vol. 476 (1997).
Teruyuki, H. et al. “Platinum-Complex-Catalyzed Double Silylation of Ethylene and Norbornene with Disilanes.”Organomet.vol. 9 (1990).
Piccoli, W. et al. “Highly Strained Cyclic Paraffin-Siloxanes.”J. Am. Chem. Soc.vol. 82 (1960).
Watanabe H. et al. “Reaction of Disilanes With Acetylenes—Double Silylation of 1-Hexyne, Trimethylsilylacetylene and Acetylene With Methoxymethyldisilanes Catalyzed by Tetrakis (Triphenylphosphine) Palladium.”J. Organmet. Chem.vol. 216 (1981).
Rahimian, K. et al. “Nonshrinking, Photopolymerizable Polycarbosiloxanes Through Ring-Opening Polymerization of Disilaoxacyclopentane Monomers.”Chem. Mater.vol. 17 (2005).

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