Method of manufacturing a trench isolation region in a...

Semiconductor device manufacturing: process – Formation of electrically isolated lateral semiconductive... – Grooved and refilled with deposited dielectric material

Reexamination Certificate

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C438S296000, C438S435000

Reexamination Certificate

active

06265284

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor device and a manufacturing method therefor, and more particularly, to a semiconductor device having a trench isolation region and a manufacturing method therefor.
2. Description of the Related Art
In a semiconductor integrated circuit, a LOCOS (LOCal Oxidation of Silicon) process in which a semiconductor substrate is oxidized using a nitride as a mask is used for isolating devices. Since an isolation layer formed by the LOCOS process is a thermal oxide, it is a densified film but ensures a low level of integration. According to the recent high integration of a semiconductor integrated circuit, a shallow trench isolation technology is widely used for overcoming the limit of integration levels of devices in case of using isolation layers formed by the LOCOS process. Hereinbelow, a conventional semiconductor device of the prior art having a trench isolation region will be described with reference to
FIG. 1A-1D
.
FIG. 1A
is a layout diagram of an active region pattern
102
and a gate electrode pattern
162
.
FIG. 1B
is a cross-sectional view taken along A-A′ direction of FIG.
1
A. Referring to
FIG. 1B
, an isolation region and an active region are formed on a semiconductor substrate
100
. Source/drain
150
, a gate insulation layer
160
, a gate electrode
162
and a gate spacer
164
are formed in the active region. Also, a side wall insulation layer
120
and an insulator burial layer
130
are formed in the trench isolation area.
FIG. 1C
is a cross-sectional view taken along B-B′ direction of FIG.
1
A. Referring to
FIG. 1C
, the side wall insulation layer
120
is formed at the side walls and on the bottom of a trench, and the insulator burial layer
130
for filling the trench is formed. Also, the gate electrode
162
is formed on the active region. A fabrication process of the semiconductor device will be described briefly. First, a buffer layer (not shown) and a photosensitive layer (not shown) are formed on the semiconductor substrate
100
and patterned. A non-active region is etched using the patterned buffer layer and the patterned photosensitive layer as a mask to form a trench. Next, the side wall insulation layer
120
is formed at the side walls and on the bottom of the trench and then the insulator burial layer
130
is formed. Next, a wet etch process is performed for removing the buffer layer. Here, since the buffer layer is formed by thermally oxidizing the semiconductor substrate
100
, the buffer layer bonding structure is densified film. However, the insulator burial layer
130
for burying the trench is an oxide formed by performing a chemical vapor deposition process at a low temperature. Thus, the insulator burial layer
130
is less denser than that of the buffer layer. As a result, when performing the wet etch process for removing the buffer layer, the insulator burial layer
130
is etched away 2-5 times faster than the buffer layer. Also, since edges of the insulator burial layer
130
adjacent to the active region are simultaneously etched at the side walls and on the upper surface thereof, the edges are etched away more than the central portion. Thus, as indicated by a region C in
FIG. 1C
, the edges of the insulator burial layer
130
are etched more deeply than the surface of the active region so that an undesired groove is formed.
FIG. 1D
is an enlarged cross-sectional view of the region C shown in FIG.
1
C. The gate electrode
162
is formed on the active region and at the side walls of the active region where the groove is formed.
Now, the operation of the device will be described. If power greater than a threshold voltage is applied to the gate electrode
162
, a channel is formed in the active region below the gate insulation layer
160
, which causes current to flow from the source to the drain. However, as shown in
FIG. 1D
, if the undesired groove is formed at the edges of the insulator burial layer
130
, the gate electrode
162
is formed on top of and at the side walls of the active region. As a result, if a voltage is applied to the gate electrode
162
, only a vertical electric field x ranging toward the upper surface of the active region is induced in the central portion of the active region. However, in the edges of the active region, both a vertical electric field y ranging toward the upper surface of the active region and a side wall electric field z ranging toward the side wall of the active region of the gate electrode
162
are induced. Thus, even if a voltage lower than a threshold voltage is applied to the gate electrode
162
, a stronger electric field is induced in the edge portion of the active region than in the central portion. As a result, even if a voltage lower than the threshold voltage is applied to the gate electrode
162
, a channel is induced in the edge portion of the active region, so that unwanted current flows from the source to the drain.
To solve the problem, that is, the device is turned on at the voltage lower than the threshold voltage, the formation of the groove in the edges of the insulator burial layer
130
must be suppressed. To this end, a wet etch time is minimized in the conventional art. However, in this case, it is difficult to keep a constant concentration of an etching solution used in the wet etch process, thereby disabling to obtain the same resultant structure.
SUMMARY OF THE INVENTION
To solve the above problems, it is an objective of the present invention to provide a method of manufacturing a semiconductor device having a trench isolation region in which a groove is not formed at edges of an insulator burial layer.
To achieve the objective, there is provided a method for manufacturing a semiconductor device comprising the steps of forming a trench by etching a predetermined portion of a semiconductor substrate, recovering the surface of the semiconductor substrate damaged due to the etching by forming a side wall insulation layer at side walls and on a bottom portion of the trench, forming an exposure prevention layer on the side wall insulation layer to prevent the side walls of the trench from being exposed to subsequent etching, and forming an insulator burial layer by depositing an insulator into the trench where the side wall insulation layer and the exposure prevention layer are formed.
At this time, the formation of the side wall insulation layer is performed by thermal oxidation. Also, the exposure prevention layer is preferably formed of a high temperature oxide (HTO) by performing a chemical vapor deposition process and the chemical vapor deposition process is performed at a temperature of 800° C. or above. The formation of the exposure prevention layer includes depositing polysilicon over the entire surface of the semiconductor substrate where the side wall insulation layer is formed, and thermally oxidizing the deposited polysilicon.
The insulator burial layer is preferably formed by performing a chemical vapor deposition process and the insulator burial layer is formed at a low temperature of 400° C. or below.
Also, after the formation of the insulator burial layer, the semiconductor substrate is annealed at a temperature of 900-1100° C.
In the semiconductor device according to the present invention, a densified exposure preventing layer is formed between the side wall insulation layer and the insulator burial layer, so that a groove exposing the surface of the semiconductor substrate is not formed between the active region where the gate electrode is formed and the trench isolation region. As a result, since only the vertical electric field is induced at edges of the gate electrode, a channel is not formed below the gate electrode when a voltage less than a threshold voltage, thereby preventing the device from being turned on.


REFERENCES:
patent: 4571819 (1986-02-01), Rogers et al.
patent: 5561073 (1996-10-01), Jerome et al.
patent: 5719085 (1998-02-01), Moon et al.
patent: 5872045 (1999-02-01), Lou et al.
patent: 5960298 (1999-09-01), Kim
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