Photocurable compositions using triarylsulfonium salts

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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20415911, 20415918, 20415923, 20415924, 430281, 430286, 430288, 528 90, G03C 168

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active

042450292

ABSTRACT:
Photocurable compositions are provided based on the use of particular triarylsulfonium salts as photoinitiators for certain oxirane containing aliphatically unsaturated organic resins, such as acrylics, or mixtures of vinyl aromatic and unsaturated polyesters. A simultaneous free-radical cure and cationic cure of the aforesaid organic resins are achieved, which provides improved results, such as metal coatings having improved solvent resistance.

REFERENCES:
patent: 3721616 (1973-03-01), Watt
patent: 3790385 (1974-02-01), Steppan
patent: 3816280 (1974-06-01), Watt
patent: 3816281 (1974-06-01), Feinberg
patent: 3895952 (1975-07-01), Schlesinger
patent: 4058400 (1977-11-01), Crivello
patent: 4058401 (1977-11-01), Crivello
patent: 4156055 (1979-05-01), Taso
Ketley et al., Polymer Preprints, 19(E) 656 (1978) ACS Meeting, Miami, Fla. Sep. 1978.

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