Photohardenable films having high resolution containing nitroso

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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20415918, 20415923, 430917, G03C 168

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active

041804031

ABSTRACT:
Photohardenable films containing a photoactivated free-radical initiator and an inhibitor system composed of a noninhibiting nitroso dimer which dissociates to inhibiting nitroso monomer characterized by a dissociation constant of about 10.sup.-2 -10.sup.-10 in solution at 25.degree. C. and a dissociation half-life of at least about 0.5 minute in solution at 25.degree. C., and having an optical density to initiating radiation of about 0.02-1.25 have high resolution after exposure at the proper energy density and time.

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Tyudesh et al, Kinetics and Catalysis, (USSR) 6, pp. 175-181 (1965).
Bluhm et al, Nature, vol. 215, pp. 1478-1479, (1967).

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