Process for producing alkoxybenzene compound and aryloxybenzene

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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534681, 544297, 548197, 548217, 548259, 548306, 548363, 549362, 549437, 558417, 558418, 558426, 560 29, 560 45, 562 58, 562452, 562453, 564 50, 564 86, 564 99, 564151, 564158, 564176, 564184, 564223, 564430, 564443, C07C23112, C07D21374

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050066609

ABSTRACT:
The present invention relates to a process for producing an alkoxybenzene compound or an aryloxybenzene compound by reacting a halogenobenzene compound with an alcohol or a phenol compound in the presence of copper or a copper compound, an amine, and a base. According to the disclosure, an alkoxybenzene compound and an aryloxybenzene compound can be produced under moderate conditions in good yield with high selectivity.

REFERENCES:
patent: 4060612 (1977-11-01), Kikumoto et al.
patent: 4603222 (1986-07-01), Tang et al.
patent: 4754068 (1988-06-01), Yamaguchi et al.
Wagner et al., "Synthetic Organic Chemistry", pp. 226-227 (1963).
Advanced Organic Chemistry, Reactions, Mechanisms, and Structure, Third Edition, Jerry March, p. 584, McGraw Hill, (1977).

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