Method of forming silicide film

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

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438655, 438683, H01L 214763, H01L 2144

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active

059638290

ABSTRACT:
A method of forming a silicide film composed of refractory metal in a certain region of a semiconductor device to be formed on a semiconductor substrate, includes the steps of (a) depositing a thin film composed of refractory metal on both a semiconductor substrate and a semiconductor device, (b) carrying out a first thermal annealing to the semiconductor substrate, semiconductor device, and refractory metal in depressurized or diluted gas atmosphere including nitrogen therein, and (c) carrying out a second thermal annealing to the semiconductor substrate, semiconductor device and refractory metal in argon gas atmosphere or high vacuum atmosphere. It is preferable that the second thermal annealing be carried out at higher temperature than the first thermal annealing. The method makes it possible to reduce a resistance of the silicide layer, and selectively form the silicide layer only on a gate electrode and a diffusion layer. In addition, the method completely avoids leak current from flowing between a gate electrode and source/drain regions of a MOS transistor.

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Mallardeau et al, "Characterization of TiSi2 Ohmic and Schottky Contacts Formed by Rapid Thermal Annealing Technology", J. Electrochem. Soc., vol. 136, No. 1, pp. 238-241, Jan. 1989.

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