Photopolymerizable composition

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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430281, 430285, 430287, 430920, 522 13, 522 14, 522 15, 522 24, 522 25, G03C 172

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active

053858077

ABSTRACT:
A photopolymerizable composition comprises: (i) a polymerizable compound carrying an addition-polymerizable unsaturated bond; (ii) a methine compound; (iii) at least one compound selected from the group consisting of: (a) compounds having carbon-halogen bonds, (b) aromatic onium salts, (c) organic peroxides, (d) thio compounds, (e) hexaaryl-biimidazoles, (f) ketooxime esters, and (g) compounds represented by the following general formula (III): ##STR1## wherein R.sup.6, R.sup.7, R.sup.8 and R.sup.9 may be the same or different and each represents a substituted or unsubstituted alkyl, aryl, alkenyl, alkynyl or heterocyclic group, provided that at least two of R.sup.6, R.sup.7, R.sup.8 and R.sup.9 may be bonded together to form a ring structure and that at least one of them represents an alkyl group; and Z.sup.+ represents an alkali metal cation or a quaternary ammonium cation. The composition has a high sensitivity to a wide range of actinic light rays extending from ultraviolet to visible light.

REFERENCES:
patent: 3563749 (1971-02-01), Munder et al.
patent: 4481276 (1984-11-01), Ishikawa et al.
patent: 4505793 (1985-03-01), Tamoto et al.
patent: 4789619 (1988-12-01), Ruckert et al.
patent: 5011760 (1991-04-01), Yamaguchi et al.
patent: 5049481 (1991-09-01), Okamoto et al.

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