Process for producing hydrogen and sulfur from hydrogen sulfide

Chemistry of inorganic compounds – Sulfur or compound thereof – Elemental sulfur

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423220, 423648R, C01B 304, C01B 1704

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active

044617550

ABSTRACT:
A novel process for producing hydrogen and sulfur via the thermal decomposition of hydrogen sulfide is disclosed. The thermal decomposition of hydrogen sulfide is accomplished by passing a hydrogen sulfide containing gas through a reaction chamber containing a refractory material that has been preheated to a temperature between about 982.degree. C. and about 1816.degree. C. so that a gas stream comprising hydrogen, sulfur and hydrogen sulfide is produced. While one reaction chamber is used for decomposition, another is being preheated with hot gases such as a sulfur dioxide-oxygen mixture from a sulfur burner. When the peak temperature in the first reaction chamber declines to a selected value, the functions of the two reaction chambers are reversed.

REFERENCES:
patent: 3962409 (1976-06-01), Kotera et al.
patent: 4302434 (1981-11-01), Hellmer et al.
M.E.D. Raymont, "Make Hydrogen from Hydrogen Sulfide", Hydrogen Processing, pp. 139-142 (1975).
E. Jorne et al., "High-Temp Methanation Tests Run", Oil & Gas Journal, vol. 78, Apr. 14, 1980, p. 120.

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