Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...
Patent
1991-06-14
1992-12-22
Schofer, Joseph L.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Plural component system comprising a - group i to iv metal...
502103, 502104, 502119, 502120, 502125, 526119, 526126, C08F 402
Patent
active
051734656
ABSTRACT:
A solid catalyst component for ethylene (co)polymerization, consisting of a particulate silica support and a catalytically active part containing titanium, magnesium, chlorine and alkoxy groups is obtained by a) preparing a solution of magnesium chloride in ethanol; b) impregnating particulate silica with said solution; c) eliminating the unabsorbed ethanol from the suspension; d) eliminating absorbed ethanol from the solid; e) interacting the resultant solid with a titanium chloride, alkoxide or chloroalkoxide; and possibly interacting with an alkylaluminium chloride. In a preferred embodiment in stage e), a silicon halide is added to improve the catalyst activity.
REFERENCES:
patent: 4421674 (1983-12-01), Invernizzi
patent: 4467044 (1984-08-01), Band
patent: 4477588 (1984-10-01), Hawley
Invernizzi Renzo
Luciani Luciano
Pondrelli Maddalena
Montedipe S.r.l.
Schofer Joseph L.
Wu David
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