Toner having negative triboelectric chargeability and image form

Radiation imagery chemistry: process – composition – or product th – Electric or magnetic imagery – e.g. – xerography,... – Post imaging process – finishing – or perfecting composition...

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430111, 430124, G03G 9097, G03G 1322

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active

061564702

ABSTRACT:
A toner having a negative triboelectric chargeability is constituted by at least a binder resin, a colorant, a wax and an organic metal compound. The toner is characterized in that: (a) the toner has an acid value of 5-35 mgKOH/g, (b) the binder resin comprises a vinyl polymer, (c) the binder resin in the toner contains a chloroform-insoluble content in an amount of 3-50 wt. %, (d) the toner contains a THF (tetrahydrofuran)-soluble content providing a GPC (gel permeation chromatography) chromatogram exhibiting a main peak in a molecular weight range of 5,000-30,000 and at least one sub-peak and/or shoulder in a molecular weight range of 2.times.10.sup.5 -15.times.10.sup.5 and including 15-70% of a component having molecular weights of 1.times.10.sup.4 -10.times.10.sup.4, and (e) the organic metal compound is an organic zirconium compound comprising a coordination or/and a bonding of zirconium and an aromatic compound as a ligand or/and an acid source selected from the group consisting of aromatic diols, aromatic hydroxycarboxylic acids, aromatic monocarboxylic acids, and aromatic polycarboxylic acids.

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