Tough, processable simultaneous semi-interpenetrating polyimides

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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Details

525432, 525436, 525903, C08J 508, C08K 304

Patent

active

053388062

ABSTRACT:
A high temperature semi-interpenetrating polymer network (semi-IPN) was developed which had significantly improved processability, damage tolerance and mechanical performance, when compared to the commercial Thermid.RTM. materials. This simultaneous semi-IPN was prepared by mixing a thermosetting polyimide with a thermoplastic monomer precursor solution (NR-150B2) and allowing them to react upon heating. This reaction occurs at a rate which decreases the flow and broadens the processing window. Upon heating at a higher temperature, there is an increase in flow. Because of the improved flow properties, broadened processing window and enhanced toughness, high strength polymer matrix composites, adhesives and molded articles can now be prepared from the acetylene endcapped polyimides which were previously inherently brittle and difficult to process.

REFERENCES:
patent: 4954578 (1990-09-01), Ree et al.
patent: 4996101 (1991-02-01), Landis et al.
patent: 5145916 (1992-09-01), Yamamoto et al.
patent: 5149746 (1992-09-01), Pater
patent: 5159029 (1992-10-01), Pater et al.

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