Process for producing allyl alcohol derivatives useful in prosta

Details Process for producing allyl alcohol derivatives useful in prosta Process for producing allyl alcohol derivatives useful in prosta

1977-02-09

1978-06-13

Jiles, Henry R.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

26034622, C07D30793

Patent

active

040948862

ABSTRACT:
A novel process for producing allyl alcohol derivatives having the formula ##STR1## wherein R.sup.1 represents a hydrogen atom or a lower alkyl group; and R.sup.2 represents an alkyl group which can have an inert substituent; and X represents a hydrogen atom, a hydroxy, an alkoxy, a tetrahydropyranyloxy or a silyloxy group; which are useful intermediates for the syntheses of prostaglandins and analogous compounds is disclosed. In the process, the allyl alcohol derivatives are produced starting from .beta.-keto-esters and azides through a series of reactions.

REFERENCES:
patent: 3975427 (1976-08-01), Untch
Evans et al., Tet. Letters No. 16, pp. 1385-1388, (1973).

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