Process for producing oxybenzoyl copolyesters

Details Process for producing oxybenzoyl copolyesters Process for producing oxybenzoyl copolyesters

1980-04-25

1982-02-16

Welsh, Maurice J.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

From phenol, phenol ether, or inorganic phenolate

528128, 528173, 528179, 528193, C08G 6302

Patent

active

043160042

ABSTRACT:
A process for producing oxybenzoyl copolyesters comprising 3 to 300 of repeating unit of the formula, ##STR1## wherein m and n are each 0 or 1, and W is --O--, --SO.sub.2 --, --S-- or --CO--, which comprises reacting a compound of the formula, ##STR2## wherein R.sup.1 is a hydrogen atom, a benzyl, lower alkyl or phenyl group, and Y is a hydrogen atom or a lower alkanoyl group, with a compound of the formula, ##STR3## wherein X is a halogen atom, in the presence of an aliphatic, alicyclic or aromatic hydrocarbon solvent having a boiling point of 100.degree. to 260.degree. C. under atmospheric pressure to produce bis(carboxyphenyl)phthalate, adding a compound of the formula, ##STR4## wherein W is --O--, --SO.sub.2 --, --S-- or --CO--, Z is a hydrogen atom or an alkanoyl group, and m and n are each 0 or 1, and optionally a compound of the formula, ##STR5## wherein R.sup.2 and R.sup.3 are each a hydrogen atom, a benzyl, lower alkyl or phenyl group, and carrying out polycondensation with the removal of the solvent and byproducts so that the polycondensation system is made substantially free from the solvent at least at the end of the polycondensation to carry out substantial bulk polycondensation.

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