Preparation of thiocarbamylsulfenamides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260239R, 2602471R, 2602471T, 26029363, 26029371, 26029385, 26032683, 260464, 260465E, 2604655R, 260567, C07C15504

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active

039857433

ABSTRACT:
Thiocarbamylsulfenamides are prepared by the reaction of an amine and monohaloamine with carbon disulfide in the presence of a base. The compounds have particular utility as accelerators in the vulcanization of unsaturated polymers.

REFERENCES:
patent: 2318482 (1943-05-01), Hanslick
patent: 2333468 (1943-11-01), Cooper
patent: 2386457 (1945-10-01), Hanslick
patent: 2421352 (1947-05-01), Paul et al.
patent: 2424921 (1947-07-01), Smith et al.
patent: 3417086 (1968-12-01), Smith et al.
Smith et al. III, J. Org. Chem. 14, (1948) pp. 935-945.
Morrison et al., Organic Chemistry, 2nd Ed., (1966), p. 748.

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