Organosilicon compositions

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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523222, 525479, 528 15, 528 31, 528 25, 556460, 556462, 556479, 26432818, 26433113, 26433117, C08L 8304

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active

050138090

ABSTRACT:
Organosilicon prepolymer compositions which are the reaction products of (a) at least one of cyclic polysiloxanes or tetrahedral siloxysilanes containing at least two .tbd.SiH groups and (b) polycyclic polyenes having at least two non-aromatic, non-conjugated carbon-carbon double bonds in their rings, wherein the total ratio of the non-aromatic, non-conjugated carbon-carbon double bonds in the rings of (b) to .tbd.SiH groups in (a) in greater than 1.8:1 and either the .tbd.SiH containing compounds (a) or the polycyclic polyenes (b) have more than two reactive sites. The organosilicon compositions are blended with (c) at least one of additional cyclic polysiloxanes, additional tetrahedral siloxysilanes or linear, short chain .tbd.SiH terminated polysiloxanes to make fluid hydrosilation compositions. These storable blends are polymerized to thermally stable thermoset polymers.

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