Inversion of 2,2-difluororibose to a 2,2-difluoroxylose and inte

Details Inversion of 2,2-difluororibose to a 2,2-difluoroxylose and inte Inversion of 2,2-difluororibose to a 2,2-difluoroxylose and inte

1989-08-15

1991-01-08

Nucker, Christine

Organic compounds -- part of the class 532-570 series

Organic compounds

Carbohydrates or derivatives

536 171, 536122, C07H 100

Patent

active

049837249

ABSTRACT:
A process and intermediates useful for the invrsion of 2-deoxy-2,2-difluororibose analogs to provide 2-deoxy-2,2-difluoroxylose analogs is described.

REFERENCES:
patent: 4526988 (1985-07-01), Hertel
patent: 4692434 (1987-09-01), Hertel
A. F. Cook et al. "Carbodiimide-Sulfoxide Reactions, VI Syntheses of 2'- and 3'-Ketouridines", Journal of American Chem. Soc., 89(11), pp. 2697-2705, (1967).
K. Onodera et al., "Oxidation of Carbohydrates . . . Pentaoxide", Carbohydrate Research 6, pp. 276-285, (1968).
L. Hertel et al., Synthesis of 2,3-dideoxy-2,2-difluoro-D-ribofuranosylnucleosides, Gordon Conference, Jul. 10, 1989.
J. S. Brimacombe, Angewandte Chemie, Int. Ed. Engl., 8(6), 401-409, (1969).

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