Selective hydrogenolysis of perhalogenated ethane derivatives

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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C07C 1710

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active

051244950

ABSTRACT:
The invention relates to the manufacture of chlorofluoroethanes of formula CF.sub.3 --CHF.sub.x Cl.sub.2-x, where x is equal to 0 or 1, by catalytic hydrogenation of a perhaloethane of formula CF.sub.3 --CF.sub.x Cl.sub.3-x.
The use of an iridium-based catalyst deposited on a support enables the selectivity to be improved.

REFERENCES:
patent: 4910352 (1990-03-01), Kondo et al.
patent: 4925998 (1990-05-01), Abraham et al.
Engelhard Catalysts and Precious Metal Chemicals Catalog 1985, pp. 6-7.
Alfa Catalog 1986, European Edition, Research Chemicals and Materials, Catalysts P-205.
Alfa Products, Research Chemicals and Materials 1990-1991, Catalysts P-13.
Hydrodechlorination . . . Over Metal Powder Catalysts and TiO.sub.2 Supported Metal and Metal Oxide Catalysts, Chemistry Express, vol. 5, No. 10, pp. 785-788 (1990), Takita et al.
Chemical Abstracts, vol. 112, No. 7, Feb. 12, 1990, p. 685, #54964s.

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