Process for the control of pH in the ethynylation of formaldehyd

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 33046

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active

042949971

ABSTRACT:
In the ethynylation of formaldehyde in the presence of a copper acetylide catalyst to produce butynediol, pH is controlled by the incremental or continuous addition of an alkali metal hydroxide and an alkali metal carbonate at an equivalent ratio of hydroxide ion to carbonate ion of 1:1-4:1.

REFERENCES:
patent: 3957888 (1976-05-01), Reiss et al.
patent: 4067914 (1978-01-01), Reiss et al.

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