Producing bis(alicyclic) thioethers

Details Producing bis(alicyclic) thioethers Producing bis(alicyclic) thioethers

1988-05-23

1989-09-12

Ceperley, Mary E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D20948

Patent

active

048661848

ABSTRACT:
3,3'-Thiobis(2,5-dihydrothiophene-1,1-dioxides) on heating with a reactive Diels-Alder dienophile undergo a reaction producing thioethers having two six-membered alicyclic rings in the molecule, such as 4,4'-thiobis(3,6-dihydrophthalic acids) or the esters, anhydrides or imides thereof, and 4,4'-thiobis(1,2,3,6-tetrahydrophthalic acids) or the esters, anhydrides or imides thereof. Both rings of the dihydrothiophene dioxides participate in the reaction, apparently by forming a tetraene structure which co-reacts with two equivalents of the dienophile to form an adduct in which each six-membered ring has one or two olefinic double bonds. During the course of the reaction, the thioether bridge remains intact. Some of the bis(alicyclic) thioethers are readily converted to the corresponding bis(aromatic)thioethers by use of known aromatization methods and systems. Various utilities for the products of the foregoing reactions are described.

REFERENCES:
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patent: 3989712 (1976-11-01), Williams, III
patent: 4054584 (1977-10-01), Williams, III
patent: 4102905 (1978-07-01), Williams, III et al.
patent: 4499285 (1985-02-01), Evans
patent: 4625037 (1986-11-01), Evans
N. Novitskaya et al., Chem. Abstracts, 86:155236f (1977).
Evans et al, Polymer Preprints (Am. Chem. Soc., Div. Polymer Chem.), 1984, 25, 268.
Williams et al, J. Org. Chem., 1978, 43, 250.

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