Si.sub.3 N.sub.4 Ceramic densified using Sc.sub.2 O.sub.3 and Si

Compositions: ceramic – Ceramic compositions – Refractory

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501152, C04B 3558

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active

044017685

ABSTRACT:
At least 1 mole % SiO.sub.2 and 1/2 mole % Sc.sub.2 O.sub.3 are used as a densification aid to provide a polyphase silicon nitride ceramic having high creep strength. The composition is within the Si.sub.3 N.sub.4 - Si.sub.2 N.sub.2 O tie line, the Si.sub.3 N.sub.4 - Sc.sub.2 Si.sub.2 O.sub.7 tie line, and the Sc.sub.2 Si.sub.2 O.sub.7 - Si.sub.2 N.sub.2 O tie line in the ternary phase diagram for the Si.sub.3 N.sub.4, SiO.sub.2, Sc.sub.2 O.sub.3 system. The phases in the sintered ceramic are Sc.sub.2 Si.sub.2 O.sub.7, and Si.sub.3 N.sub.2 O, and at least 50 mole % Si.sub.3 N.sub.4.

REFERENCES:
patent: 3833389 (1974-09-01), Komeya et al.
patent: 4046580 (1977-09-01), Ishii et al.
patent: 4234343 (1980-11-01), Andersson
F. F. Lange, B. I. Davis, D. R. Clarke, "Compressive Creep of Si.sub.3 N.sub.4 /MgO Alloys", Journal of Materials Science 15 (1980), pp. 601-610.
F. F. Lange, "Silicon Nitride Polyphase Systems: Fabrication, Microstructure, and Properties", International Metals Reviews, 1980, No. 1, pp. 1-20.

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