Hydrocarbon conversion with an acidic multimetallic catalytic co

Details Hydrocarbon conversion with an acidic multimetallic catalytic co Hydrocarbon conversion with an acidic multimetallic catalytic co

1975-05-05

1976-05-25

Gantz, Delbert E.

Mineral oils: processes and products

Chemical conversion of hydrocarbons

Reforming

208111, 252441, 2606833, 26068368, 252439, C10G 3508, C01G 1308, B01J 2706, C07C 524

Patent

active

039591212

ABSTRACT:
Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, an indium component, a cobalt component, and a halogen component with a porous carrier material. The platinum group component, indium component, cobalt component, and halogen component are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % indium, about 0.05 to about 5 wt. % cobalt, and about 0.1 to about 3.5 wt. % halogen. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum group metal is present therein in the elemental metallic state, substantially all of the catalytically available cobalt component is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions, or in a mixture of these states, while substantially all of the indium is present therein in an oxidation state above that of the elemental metal. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the acidic multimetallic catalyst disclosed herein at reforming conditions.

REFERENCES:
patent: 3177160 (1965-04-01), Rosset
patent: 3193348 (1965-07-01), Mooi
patent: 3377269 (1968-04-01), Bloch
patent: 3759823 (1973-09-01), Davies et al.
patent: 3793232 (1974-02-01), Duhaut et al.
patent: 3833516 (1974-09-01), Sawyer
patent: 3880748 (1975-04-01), Sawyer
patent: 3892657 (1975-07-01), Wilhelm

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