Titanyl phthaloycyanine crystal, method of manufacture thereof a

Radiation imagery chemistry: process – composition – or product th – Electric or magnetic imagery – e.g. – xerography,... – Radiation-sensitive composition or product

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430 58, 430135, 540141, G03G 506

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052139298

ABSTRACT:
A new composition of titanyl phthalocyanine is provided. This composition has in its infrared absorption spectrum characteristically strong absorptions at absorption wavenumbers (in unit of cm.sup.-1) of 1490.+-.2, 1415.+-.2, 1332.+-.2, 1119.+-.2, 1072.+-.2, 1060.+-.2, 961.+-.2, 893.+-.2, 780.+-.2, 751.+-.2 and 730.+-.2, and has an extremely high solvent stability and dispersibility, and a large photoelectric conversion efficiency. The new form of composition can be obtained by adding to titanyl phthalocyanine, compounds of other phthalocyanines or naphthalocyanines as additives, and treating the amorphous composition of the mixture to crystallize the composition. By applying an appropriate binder, with the novel composition crystals as a charge generation agent, on a substrate, it is possible to obtain an electrophotographic photosensitive material that has a charge generation layer with an extremely high dispersibility and an extremely large photoelectric conversion efficiency.

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