Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...
Patent
1985-07-01
1987-08-04
Schwartz, Richard A.
Organic compounds -- part of the class 532-570 series
Organic compounds
Heterocyclic carbon compounds containing a hetero ring...
546210, 548309, 585270, 585276, 585277, C07D23372
Patent
active
046847359
ABSTRACT:
There is disclosed a number of processes for the promotion of the Raney Nickel catalyzed hydrogenation of carbon-carbon double bonds. (a) One process uses tertiary amines to promote the Raney Nickel catalyzed hydrogenation. (b) Another process uses acetylene and acetylene derivatives to promote the Raney Nickel catalyzed hydrogenation. The promotion of Raney Nickel catalyst is particularly suited for the reduction of unsaturated hydantoins to saturated hydantoins and also for the reduction of cyclic and acyclic olefins and diolefins to the corresponding cyclic and acyclic alkanes.
REFERENCES:
patent: 2479065 (1949-08-01), Gresham
Bond, H., J. Biol. Chem., 175, 531-4 (1948).
Chemical Abstracts, 88: 177763u (1978) [Matviichuk, A., et al., Deposited Doc. 1976, Viniti 1667-76].
Pizey, J., Synthetic Reagents, vol. II, Malsted Press, NY, 1974, pp. 180-181, 188-193 and 290.
Doyle, F., et al., J. Chem. Soc., 1955, p. 2271.
Ward, H., J. Am. Chem. Soc., 74, 4212 (1952).
Borrows, E., et al., J. Chem. Soc., 1949, S185.
Levering, D., et al., J. Am. Chem. Soc., 72, 1190 (1950).
Tucker, S., J. Chem. Ed. 1950, 489.
Dominguez, N., et al., J. Org. Chem., 24, 1625 (1961).
Walter, L., et al., J. Am. Chem. Soc., 63, 2772 (1941).
R. Augustine, Catalytic Hydrogenation, Marcel Dekker, Inc., New York, 1965, p. 32.
M. Freifelder, Practical Catalytic Hydrogenation, Wiley-Interscience, New York, 1971, pp. 32, 41, 44, 45, 46, 48, 52, 53, 84, 87, 91, 92, 94, 95 and 96.
L. Fieser et al., Organic Chemistry, 2nd ed., D. C. Heath, Boston, 1950, pp. 221-224.
P. Rylander, Hydrogenation Methods, Academic Press, London, 1985, p. 53.
Pauling, L., The Nature of the Chemical Bond, Cornell J. Press, Ithaca, 1960, p. 275.
Whitmore, F., Organic Chemistry, 2nd ed., D. Van Nostrand, New York, 1951, pp. 295 and 493.
Juettner Paul J.
Schwartz Richard A.
Stauffer Chemical Company
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