Process for the preparation of 1-aminoanthraquinones

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260384, 260371, 260373, 260380, 260381, C07C 9724, C07C 9726, C07C143665

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active

043281605

ABSTRACT:
A selective process for the preparation of 1-aminoanthraquinones from the corresponding 1-aminoanthraquinone-2-carboxylic acid by decarboxylation in basic solution in the presence of iron, tin or zinc as a catalyst.

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Chemical Abstracts, vol. 71, 1969, Abstract No. 48900m, Long "Mechanisms for Decarboxylation of Aromatic Acids".
Chemical Abstracts vol. 74, 1974, Abstract No. 52664s, p. 268, Manikyam "Thermal Decarboxylation of Benzoic Acids".
Chemical Abstracts vol. 74, 1971, Abstract No. 64020s, p. 287, Chodowska-Palicka "Decarboxylation of 2 Nitro Benzoic Acids".
Chemical Abstracts, vol. 67, 1967 Abstract No. 43191p, p. 4036, Rekker et al. "Decarboxylation of Substituted 4-Amino Benzoic Acid in Aqueous Solution".
Chemical Abstracts, vol. 85, 1976, Abstract No. 177120v, p. 495, Morley, "Synthesis of Aminoanthraquinones by Sodium Borohydride Reduction of Nitroanthraquiones".

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