Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system
Patent
1984-07-26
1986-07-22
Ramsuer, Robert W.
Organic compounds -- part of the class 532-570 series
Organic compounds
Four or more ring nitrogens in the bicyclo ring system
544404, 564408, 564445, 564467, C07C 8508, C07D29502
Patent
active
046020888
ABSTRACT:
A method for the preparation of enamines wherein a conjugated diene is reacted with a secondary amine, carbon monoxide and hydrogen (synthesis gas) in solvent solution in the presence of a rhodium catalyst. In accordance with the preferred embodiment, butadiene is reacted with a dialkylamine and synthesis gas in an organic solvent in the presence of a rhodium catalyst to provide the corresponding 1,3-pentadienyl dialkylamine in good yield and with good selectivity. This may be illustrated, for example, by the following equation: ##STR1##
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Park Jack H.
Priem Kenneth R.
Ramsuer Robert W.
Texaco Inc.
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