Preparation of tertiary amines

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260563R, 260563C, 2605708R, 2605709, 260576, 260583R, C07C 8508

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042072603

ABSTRACT:
Tertiary amines may be prepared by reacting an aldehyde, hydrogen and a nitrogen-containing compound such as ammonia, a primary amine or a secondary amine in the presence of a rhodium- or ruthenium-containing catalyst at temperatures in the range of from about 50.degree. to about 350.degree. C. and a pressure in the range of from about 10 to about 300 atmospheres.

REFERENCES:
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patent: 2219879 (1940-10-01), Vanderbilt
patent: 2452602 (1948-11-01), Robinson et al.
patent: 2477943 (1949-08-01), Robinson et al.
patent: 3091641 (1963-05-01), Sweeney
patent: 3336386 (1967-08-01), Dovell et al.
patent: 3597438 (1971-08-01), Blake
patent: 3658824 (1972-04-01), Thoma et al.
patent: 3758586 (1973-09-01), Coulson
patent: 3864382 (1975-02-01), Funten et al.
Ginsburg, "Concerning Amines", pp. 33-38, (1967).

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