Process for preparing oxabicycloalkane compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D49308

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active

045543658

ABSTRACT:
The invention provides a process for preparing a 7-oxabicyclo[2.2.1]heptan-2-ol, which comprises treating a liquid-phase mixture of the corresponding cyclohex-3-en-1-ol, an aldehyde containing at least two carbon atoms and a suitable solvent, with oxygen in the presence of a catalyst which is soluble in the reaction mixture and which comprises a praseodymium compound and at least one compound selected from compounds of molybdenum, niobium, tantalum, tungsten, uranium and vanadium.

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