Epoxy/nucleophile transesterification catalysts and thermoset co

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

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523428, 525340, 525379, 528 93, C08L 6300

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active

047497289

ABSTRACT:
A new transesterification catalyst comprises an epoxide and a non-acidic nucleophilic onium salt.
Coating compositions having hydroxyl functional resin components and carboxylic ester components adapted for curing by transesterification following application to a substrate are formulated with in-situ formed cure catalyst comprising a non-acidic nucleophile and an epoxide-to-product coatings that readily cure by transesterification. Such coatings including polyesters, polyepoxides, and polyacrylates are useful in formulating high solids coatings and powder coatings having exceptional physical properties.
Extremely low-temperature cure coatings were obtained by transesterifying mixtures of polyols and polymeric esters having multiple activated ester linkages having the structure ##STR1## wherein R' is lower alkyl and Y is --OH and O-alkyl radicals. These coatings provide low-temperature cure coatings for paper, plastic, and wood in addition to metal substrates.

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