Process for preparing optically active polymer

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526173, 526180, 526181, 526183, 526185, 526189, 526328, 526265, 5263031, C08F 446, C08F 450, C08F 452

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active

045543348

ABSTRACT:
An optically active polymer is obtained by polymerizing a vinyl monomer in the presence of a catalyst which comprises an asymmetric ligand compound of the formula (I) or (II): ##STR1## in which R.sub.1 and R.sub.4 each are --O--R.sub.7, --S--R.sub.7, ##STR2## R.sub.2, R.sub.3, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 each are an alkyl group having 1 to 10 carbon atoms; X is hydrogen, an alkyl group having 1 to 10 carbon atoms or a halogen; and n is a number of 1 to 4; and an anionic initiator to form a complex with said ligand compound.

REFERENCES:
patent: 4107418 (1978-08-01), Yatsu
patent: 4230841 (1980-10-01), Prudence

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