Method for hydrogenating aqueous solutions of carbohydrates

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 3126, C07C 3124, C07C 3118

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043806805

ABSTRACT:
Zerovalent Group VIII metals dispersed on alpha-alumina are hydrothermally stable hydrogenation catalysts which may be used advantageously in the reduction of aqueous solutions of carbohydrates. The use of ruthenium on alpha-alumina in the hydrogenation of glucose affords sorbitol in excellent yields with quite high selectivity, and with minimal leaching of either ruthenium or alumina.

REFERENCES:
patent: 2752399 (1956-06-01), Grimme et al.
patent: 3651221 (1972-03-01), Conrad et al.
patent: 3963788 (1976-06-01), Kruse et al.
patent: 3963789 (1976-06-01), Kruse et al.
patent: 4072628 (1978-02-01), Kruse et al.

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