Optically active tert-alkyl 7-(2-oxo-5-carbonyloxypyrrolidinyl)h

Details Optically active tert-alkyl 7-(2-oxo-5-carbonyloxypyrrolidinyl)h Optically active tert-alkyl 7-(2-oxo-5-carbonyloxypyrrolidinyl)h

1981-12-09

1983-08-16

Fan, Jane T.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D20728

Patent

active

043992900

ABSTRACT:
Optically active tert-alkyl 7-2(oxo-5-carbonyloxypyrrolidinyl)heptanoates and their preparation by reaction of racemic tert-alkyl 7-(2-oxo-5-carboxypyrrolidinyl)heptanoate with an optically active amine to form resolved d or l amine salts which are then reacted with acid to form resolved acid intermediates. Esterification of these acid intermediates produces resolved d or l esters which are useful to make optically active 8-azaprostanoids having biological activity.

REFERENCES:
patent: 3965143 (1976-06-01), Collins et al.

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