Method of converting amine hydrohalide into free amine

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Preparing inorganic compound

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204539, 204630, 204632, 204536, C25B 100, C25B 900, C25B 700

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058825010

ABSTRACT:
Describes a method of electrochemically converting amine hydrohalide, e.g., ethyleneamine hydrochloride, into free amine, e.g., free ethyleneamine, by charging an aqueous solution of amine hydrohalide to the catholyte compartment of an electrolytic cell, which contains a cathode, charging hydrogen gas to the anode compartment of the cell, which contains an anode assembly comprised of a hydrogen consuming gas diffusion anode fixedly held between a current collecting electrode and an anion exchange membrane. The catholyte and anode compartments of the cell are separated by the anion exchange membrane. An amine hydrohalide solution containing free amine is removed from the catholyte compartment.

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