Process for the preparation of fluorine-substituted carboxylic a

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260544Y, 260544S, 260544B, C07C 5158

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active

044204337

ABSTRACT:
Fluorine substituted carboxylic acid chlorides are prepared from the corresponding fluorine substituted carboxylic acid fluorides by reaction with silicon tetrachloride, or titanium tetrachloride, optionally in the presence of a catalyst. The so-prepared fluorine substituted carboxylic acid chlorides can in turn be readily converted to fluorine substituted aldehydes by reduction with hydrogen in the presence of palladium as catalyst.

REFERENCES:
patent: 944372 (1909-12-01), Mugdan
patent: 3694499 (1972-09-01), Quarles
patent: 3706773 (1972-12-01), Anello et al.
patent: 3725475 (1973-04-01), Paucks
patent: 4136113 (1979-01-01), Johnston

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