Process for producing aromatic amines by reduction of aromatic n

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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546171, 546311, 548301, 552236, 552238, 562 58, 564 86, 564416, 564417, 564418, 564420, C07C20936

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050877550

ABSTRACT:
A process for producing an aromatic amine under moderate conditions is provided wherein a catalyst higher in activity than conventional catalysts is used. Reduction of an aromatic nitro compound under a CO/H.sub.2 O system is conducted using a rhodium compound catalyst in the presence of an aqueous alkali solution such as aqueous sodium hydroxide solution. Alternatively, an aromatic nitro compound is reduced under a CO/H.sub.2 O system using a rhodium compound or a ruthenium compound catalyst in the presence of the aqueous alkali solution and additionally at least one compound of amine compounds, diamine compounds, phosphine compounds, phosphite compounds, and diphosphine compounds.

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