Preparation of propanone-1,3-disulfonic acid

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfonic acids or salts thereof

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C07C30905

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054301807

ABSTRACT:
Propanone-1,3-disulfonic acid (acetone disulfonic acid) may be prepared by reacting chlorosulfonic acid with acetone preferably in the presence of a solvent for the reactants, such as methylene chloride, although a neat reaction is possible. The reactants and reaction conditions prior to separation should be substantially anhydrous, but water may be added after reaction to separate the product as an aqueous solution.

REFERENCES:
Gilbert Sulfonation and Related Reactions (1965) pp. 37-41.
Chem Abst. 45, 8445i (1951) Terentev et al.
J. Org Chem 30, 515-517 (1965) Grot.

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