Process for synthesizing alkyl monoperoxysuccinic acid bleaching

Details Process for synthesizing alkyl monoperoxysuccinic acid bleaching Process for synthesizing alkyl monoperoxysuccinic acid bleaching

1984-07-02

1987-04-21

Lieberman, Paul

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

25218626, 252 95, 252 99, 252102, 8111, C07C 8700

Patent

active

046595198

ABSTRACT:
The invention relates to a novel process for synthesizing surface active peroxyacid bleaching agents and compositions which are named .alpha. or .beta. alkyl monoperoxysuccinic acids and have the general structure ##STR1## wherein R is an unsubstituted or substituted straight chain alkyl of 6 to 16 carbon atoms, unsubstituted or substituted branched chain alkyl of 6 to 20 carbon atoms, or a phenyl group substituted with one or more of H, alkyl of 1 to 14 carbon atoms, F, Cl, NO.sub.3, OSO.sub.3 M, SO.sub.3 M, or COOM, and M is further defined as H, an alkali metal or ammonium cation.
The invention provides a novel process for synthesizing these alkyl monoperoxysuccinic acids which is relatively inexpensive, high yielding, and safe.
The bleaching compositions are useful for bleaching fabrics and other laundering purposes. The bleaching compositions of the invention may also contain peroxyacid stabilizers, builders, fillers, and surfactants.

REFERENCES:
patent: 2287064 (1942-06-01), Reichert et al.
patent: 3075921 (1963-01-01), Brocklehurst et al.
patent: 3143562 (1964-08-01), Silbert et al.
patent: 3321512 (1967-05-01), Cooper et al.
patent: 3494786 (1970-02-01), Nielsen
patent: 3494787 (1970-02-01), Lund et al.
patent: 3639285 (1972-02-01), Nielsen
patent: 3655738 (1972-04-01), Nielsen
patent: 3770816 (1973-11-01), Nielsen
patent: 3819688 (1974-06-01), Silbert et al.
patent: 3880914 (1975-04-01), Nielsen
patent: 3956159 (1976-05-01), Jones
patent: 3975280 (1976-08-01), Hachmann et al.
patent: 4006029 (1977-02-01), Guile et al.
patent: 4013575 (1977-03-01), Castrantas et al.
patent: 4085133 (1978-04-01), Briody
patent: 4088676 (1978-05-01), Hofen et al.
patent: 4091544 (1978-05-01), Hutchins
patent: 4100095 (1978-07-01), Hutchins et al.
patent: 4119660 (1978-10-01), Hutchins
patent: 4126573 (1978-11-01), Johnston
patent: 4170453 (1979-10-01), Kitko
patent: 4172086 (1979-10-01), Berkowitz
patent: 4233235 (1980-11-01), Camden et al.
patent: 4244884 (1981-01-01), Hutchins et al.
patent: 4259201 (1981-03-01), Cockrell, Jr. et al.
patent: 4287135 (1981-09-01), Stober et al.
patent: 4314949 (1982-02-01), Bettie, III et al.
patent: 4337213 (1982-06-01), Marynowski et al.
patent: 4370251 (1983-01-01), Liao et al.
patent: 4374035 (1983-02-01), Bossu
patent: 4385008 (1983-05-01), Hignett
patent: 4391723 (1983-07-01), Bacon et al.
patent: 4391724 (1983-07-01), Bacon
patent: 4391725 (1983-07-01), Bossu
patent: 4443352 (1984-04-01), Broze et al.
A. Ault, Techniques and Experiments for Organic Chemistry, 2nd Ed., 1976, pp. 19-28.
S. N. Lewis, "Peracid and Peroxide Oxidations," in: Oxidation, 1969, pp. 213-258.
K. Balenovic et al, "Asymmetric Synthesis of Sulphoxides with .alpha.-Substituted Monoperglutaric Acids," Chemistry and Industry, Apr. 15, 1961, pp. 469-470.
M. F. Hawthorne et al, "A Re-Examination of the Peroxyacid Cleavage of Ketones. II. Kinetics of Baeyer-Villiger Reaction," J.A.C.S., vol. 80, pp. 6398-6404, (1958).
M. F. Hawthorne et al, "A Re-Examination of the Peroxyacid Cleavage of Ketones. I. Relative Migratory Aptitudes," J.A.C.S., vol. 80, pp. 6393-6398, (1958).
W. E. Parker et al, "Peroxides. IV. Aliphatic Diperacids," J.A.C.S., vol. 79, pp. 1929-1931, (1957).
D. Swern et al, "Peroxides. III. Structure of Aliphatic Peracids . . . Etc.," J.A.C.S., vol. 77, pp. 5537-5541, (1955).
W. D. Emmons et al, "Peroxytrifluoroacetic Acid. III. The Hydroxylation of Olefins," J.A.C.S., vol. 76, pp. 3472-3474, (1954).
W. D. Emmons, "Peroxytrifluoroacetic Acid. II. The Oxidation of Anilines to Nitro-Benzenes," vol. 76, pp. 3470-3472, (1954).
W. D. Emmons, Peroxytrifluoroacetic Acid. I. The Oxidation of Nitrosamines to Nitramines," J.A.C.S., vol. 76, pp. 3468-3470, (1954).
D. Swern, Organic Peroxides, vol. 1, p. 405, (1970).

Affiliated with

Also associated with

Rating

Process for synthesizing alkyl monoperoxysuccinic acid bleaching does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for synthesizing alkyl monoperoxysuccinic acid bleaching, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for synthesizing alkyl monoperoxysuccinic acid bleaching will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-750398