Process for the preparation of alkylthiomethylphenols and arylth

Details Process for the preparation of alkylthiomethylphenols and arylth Process for the preparation of alkylthiomethylphenols and arylth

1980-12-01

1982-11-09

Gerstl, Robert

Organic compounds -- part of the class 532-570 series

Organic compounds

Sulfur containing

568 44, 568 49, 568 50, 568 51, 568 52, 568 54, C07C14800

Patent

active

043586163

ABSTRACT:
The present invention provides a process for the preparation of an alkylthiomethylphenol or arylthiomethylphenol of the general formula ##STR1## in which m, n, R and R.sup.1 have the meaning mentioned in the specification, in which a hydroxymethylphenol of the general formula ##STR2## is reacted with a mercaptan or thiophenol at a temperature of from 20.degree. to 200.degree. C., if appropriate in the presence of a diluent.

REFERENCES:
patent: 2831030 (1958-04-01), Chenicek
patent: 3179701 (1965-04-01), Rocklin
patent: 3553270 (1971-01-01), Wollensak et al.
patent: 3903173 (1975-09-01), Eggensperger et al.
patent: 4304940 (1981-12-01), Wedemeyer et al.
Rudermann, et al., J. Am. Chem. Soc., 71(2), p. 264, (1949).
Poppelsdorf, et al., J. Chem. Soc. (1954), pp. 1124-1130.
Wagner, et al., "Lackunstharze", pp. 33-37, Munich, (1971).
Miyamoto, et al., Chemical Abstracts, 82, 86197x (1975).
Houben-Weyl, vol. 6/1C, 4th ed., p. 1042 (1976).

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