Polyesters compositions which crystallize rapidly

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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264239, 264176R, 524730, 528272, 528302, 5283082, 5283086, C08F28300, C08G 6376, C08L 6700

Patent

active

044355467

ABSTRACT:
Polyalkylene terephthalates containing 0.5-30% by weight of monomeric aliphatic carboxylic acid esters have a higher crystallization speed and thus allow lower mold temperatures and shorter injection cycles. The polyalkylene terephthalates generally have intrinsic viscosities in excess of about 0.4 dl/g in 1:1 phenol tetrachloroethane at 25.degree. C. and are at least about 90 mol % terephthalic acid based. The ester additive is based on aliphatic cycloaliphatic or araliphatic carboxylic acids, with sebacic and adipic being preferred, and aliphatic, cycloaliphatic or araliphatic alcohols.
Faster crystallization rates can be imparted to polyalkylene terephthalates by mixing them with the ester additive and melt homogenizing the mixture.

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