Process for preparing spherical and porous vinyl resin particles

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Cellular products or processes of preparing a cellular...

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428402, 521 56, 526 88, 526209, 5263442, 5263443, C08V 928

Patent

active

044355246

ABSTRACT:
Process for making porous, substantially spherical particles having high bulk density of vinyl polymers or resins by the use of the suspension polymerization technique. In the polymerization there is employed a water-insoluble dispersant comprised of a substantially unneutralized crosslinked interpolymer of one or more carboxylic acid monomers with a polyunsaturated compound having a plurality of terminally unsaturated polymerizable groups and a surfactant system comprising at least one surfactant selected from the group consisting of a polyethylene oxide containing surfactant and a non-polyethylene oxide containing surfactant. Excellent results are obtained when both a polyethylene oxide and a non-polyethylene oxide containing surfactant are used in the process of the invention. Rapid stirring or high agitation is used while employing a monomer-soluble free radical yielding polymerization catalyst.

REFERENCES:
patent: 4360651 (1982-11-01), Dinbergs

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